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Part I-Variations of the Physical Properties with Time

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The Relation between the Physical Properties and the Structure of Glass. Part I. Variations of the Physical Properties with Time

JSGT 1947 V31 T050-T073

The X-ray diffraction patterns of liquids and glasses are compared; it is shown that the similarities between them enable a qualitative application to be made to glasses of some theoretical work on the liquid state by J. D. Bernal. In this way a satisfactory account may be given of the time-variation of the physical properties of glasses in the temperature range in which their viscosity increases above about 1013 poises. This account is given in terms of a random network structure and involves no considerations of aggregation or association.

R. W. Douglas

Society of Glass Technology

9 Churchill Way, Chapeltown, Sheffield S35 2PY, Telephone 0114 2634455